What compound is produced when (R)-pentan-2-ol is treated with TsCl followed by NaI? Provide the major organic product of the following. No reaction. Predict the major product of the following dehydration reaction. A blue-green color in either layer indicates a positive test. K2Cr2O7/acetic acid 2. H2SO4/heat, Which of the following reaction series will result in the formation of a new secondary (2°) alcohol from the beginning alcohol listed at the top? This is considered a "positive" test result, and in this case indicates the presence of a functional group that can be … Procedure: Add 2mL of 5%NaHCO 3(aq) into a test tube and add 5 drops or 50mg of your sample. Draw a structure for the expected product of the reaction below. Which of the following reactions or series of reactions would reduce 3-methylbutan-2-ol into 2-methylbutane? Extensive resonance stabilization of this ion makes it a particularly good leaving group. Use the Lucas test. Poisonings by methanol and ethylene glycol are relatively common. Provide the major organic product of the reaction shown. Figure 6.51: Reaction of carboxylic and sulfonic acids with bicarbonate ion. PhCH2CH(OH)CH3. Hg(OAc)2 (aq) 3. K2Cr2O7/acetic acid 2. What series of synthetic steps could be used to prepare hexan-3-ol from propan-1-ol? The enzyme, alcohol dehydrogenase, which is produced by the liver, converts ethanol to ________, a normal body metabolite. In the formation of the following ether, which reaction is preferred and why. For example, addition of an orange chromic acid reagent to some compounds causes the chromium reagent to change to a blue-green color (Figure 6.37a). Chromic acid features chromium in an oxidation state of +6 (or VI). Provide a detailed, stepwise mechanism for the reaction below. Provide the necessary reagents for the following conversion. tert-butanol. It is a strong and corrosive oxidising agent. cyclohexanol. Which of the following alcohols will give a positive chromic acid test? What is the major organic product when n-butanol reacts with hydrochloric acid? Draw a mechanism for the following reaction. ) To ensure the best experience, please update your browser. This is a pinacol rearrangement reaction where the most stable carbocation would be formed at the tertiary position in the ring. Provide the structure of the major organic product that results when 4-methyl-1-pentanol is treated with PBr3. NaBH4 E) 2-methylcycloxexanol 1. Provide the major organic product of the following reaction. (f) Test with Chromic Acid: Take the given organic compound in a clean test tube. Nitroglycerine is formed by the reaction of glycerine (propane-1,2,3-triol) and nitric acid. Tertiary alcohols are not oxidized by PCC. 1) HBr, ROOR 2) NaCN or 1) BH3 2) H2O2, -OH 3) HBr or PBr3 4) NaCN. LiAlH4. Provide the major organic product of the reaction shown. Provide the name of the major organic product that results when cyclopentanol is treated with acetyl chloride. Chromic acid may also refer to the molecular species, H2CrO4 of which the trioxide is the anhydride. Provide the structure of the major organic product in the reaction below. H2SO4/heat 2. Octyl acetate (shown below) is an ester that has a strong orange odor. The Williamson ether synthesis proceeds via an ________ mechanism. What series of synthetic steps could be used to prepare PhCH(OH)CH2CH3 from, What series of synthetic steps could be used to carry out the transformation shown below. What is the best way to make the ether shown below using a Williamson Ether Synthesis reaction? How could tell a sample of n-butanol from tert-butanol? NaH; 2. What type of linkage bonds the individual nucleotides together in DNA? A positive test for carboxylic acids is the formation of bubbles or frothing (Figure 6.52). Mix the solution by agitating the test tube. This kind of chromic acid may be used as a cleaning mixture for glass. CH3-MgBr 3. H2SO4/heat 2. OsO4/H2O2 3. Expert Answer 100% (2 ratings) Previous question Next question Get more help from Chegg. What is the major organic product of the following reaction? CH3CH2I B) t-butyl alcohol 1. Explain briefly. Na° 2. If the patient receives intravenous infusions of ethanol, then the ethanol swamps the enzyme and the potentially deadly alcohols pass from the body unoxidized. Provide the name of the major organic product that results when trans-4-methylcyclohexanol is treated with thionyl chloride. What is the final product of the reaction sequence shown below, making sure to include stereochemistry as appropriate. CH3(CH2)6CH2OH + HBr →, Predict the major product of the reaction below and provide a stepwise mechanism which accounts for its formation. Provide the major organic product of the reaction shown. Which of the following reagents is not typically viewed as an oxidizing agent? The term chromic acid is usually used for a mixture made by adding concentrated sulfuric acid to a dichromate, which may contain a variety of compounds, including solid chromium trioxide. It looks like your browser needs an update. (CH3)3CCH2OH + HBr →. How are these poisonings treated clinically? What is the product of the following reaction? PhCH2CH2OH →, Provide the structure of the major organic product in the reaction below. Classify the reaction below as an oxidation, a reduction, or neither. Identify the sequence of reactions that successfully completes the following transformation. No reaction occurs; Tertiary alcohols are resistant to mild oxidation conditions. Complete the following reaction by filling in the necessary reagents. Which of the following reagents can be used to convert cyclopentanol to cyclopentane? Which of the following reagents is the best choice for oxidizing a primary alcohol … Predict the outcome of the following reaction. 1) Br2, hν 2) NaOEt, heat 3) BH3 4) H2O2, -OH 5) PCC. H2SO4/heat. Hg(OAc)2 (aq) 3. With close attention to stereochemistry, provide the major organic product for the reaction shown below. The carbocation formed in this reaction is a tertiary carbocation and substitution is too sterically hindered. Which of the following alcohols will give a positive chromic acid test? (CH3)2CHCH2OH. What is the expected product of the reaction below. Given a sample of (R)-2,3-dimethylhexan-3-ol, which of the following would be the best synthesis of (R)-3-chloro-2,3-dimethylhexane? Note that if the unknown is not soluble in water, two layers may be present. Provide the name of the major organic product that results when (R)-2-methyl-3-pentanol is heated with conc. CH3CH2Br. Provide a detailed, stepwise mechanism for this process. Which of the following alcohols undergoes dehydration upon heating with concentrated H2SO4 without carbocation rearrangement? Methods to do this include protonation, conversion to the tosylate ester, and conversion to the halide. Which of the following compounds has carbon in the highest oxidation state? Through what basic mechanism is 1-methylcyclohexanol converted to 1-bromo-1- methylcyclohexane upon treatment with HBr? Which of the following reagents is the best choice for oxidizing a primary alcohol to an. What is the product of the reaction shown below? 1) Na2Cr2O7 / H2SO4 2) EtOH / acid catalyst.